Nature inspired singlet oxygen generation to access α-amino carbonyl compounds<i>via</i>1,2-acyl migration
Waldemar Schilling, Yu Zhang, Prakash Kumar Sahoo, Samir Kumar Sarkar, Gandhi Sivaraman, Herbert W. Roesky, Shoubhik Das
Abstract
We have discovered chlorophyll catalyzed 1,2-acyl migration reactions to achieve α-amino carbonyl compounds directly from the enaminones.
Topics & Concepts
Singlet oxygenChemistryCarbonyl ironCombinatorial chemistryPhotochemistryCarbonyl groupOxygenMedicinal chemistryOrganic chemistryMaterials scienceComposite materialAsymmetric Synthesis and CatalysisCatalytic C–H Functionalization MethodsOxidative Organic Chemistry Reactions