The effect of adding green synthesized and commercial silver nanoparticles to biodiesel on diesel engine performance and emissions
Üsame Demir, Merve Keskin, Salih Özer, Gökhan Coşkun
Abstract
This study evaluates the impact of silver nanoparticles synthesized via a green method using Humulus lupulus L. and commercial silver nanoparticles (CAS: 7440-22-4) on biodiesel performance and emissions in diesel engines. Biodiesel from waste cooking oil was tested under partial load (1–4 kW) with the following blends: 100 % diesel (D), 50 % diesel-50 % biodiesel (BD50), biodiesel with green-synthesized nanoparticles (200, 400, 600 ppm: B_G200, B_G400, B_G600), and biodiesel with commercial nanoparticles (200, 400, 600 ppm: B_C200, B_C400, B_C600). The results showed that green-synthesized nanoparticles significantly reduced CO emissions (up to 71.42 % at 4 kW for B_G600), HC emissions (48.88 %), and particulates. Combustion efficiency improved, increasing CO 2 emissions (peak 2.59 % for B_G600 at 4 kW). However, exhaust temperatures rose (583 °C for B_G600), and NO x emissions increased, peaking at 237 ppm for B_G400 at 4 kW. Green nanoparticles were more effective than commercial ones in reducing CO, HC, and particulate emissions while enhancing combustion. However, increased CO 2 and NO x emissions suggest the need for further optimization. This study highlights green nanotechnology's potential to improve biodiesel performance sustainably while addressing environmental challenges.