Kinetic and Mechanistic Studies of the Formation of Silver Nanoparticles by Nicotinamide as a Reducing Agent
Indresh Kumar, Chinky Gangwar, Bushra Yaseen, Pradeep Pandey, Sheo K. Mishra, Radhey Mohan Naik
Abstract
) versus time exhibited a straight line and the pseudo-first-order rate constants of different variables were calculated from its slope. On the basis of experimental findings, a plausible mechanism was proposed for the formation of SNPs colloid. From the mechanism, it is proved that the reduction of silver ions proceeded through the formation of silver oxide in colloidal form by their reaction with hydroxide ions and NTA after performing their function and readily undergo hydrolysis to form nicotinic acid as a hydrolysis product with the release of ammonia gas. The preliminary characterization of the SNPs was carried out by using a UV-visible spectrophotometer. The detailed characterization of SNPs was also carried out using other experimental techniques such as Fourier transform infrared spectroscopy (FTIR), field-emission scanning electron microscopy (FESEM), energy-dispersive X-ray spectroscopy (EDS), transmission electron microscopy (TEM), and powder X-ray diffraction (PXRD). SNPs show a remarkable catalytic activity of up to 90% for the reduction of the cationic dye methylene blue.