Design, synthesis, structural, spectral, and redox properties and phenoxazinone synthase activity of tripodal pentacoordinate Mn(<scp>ii</scp>) complexes with impressive turnover numbers
Sadananda Kumbhakar, Bishnubasu Giri, Arabinda Muley, Kalai Selvan Karumban, Somnath Maji
Abstract
Two mononuclear pentacoordinate manganese complexes with the molecular framework [Mn II (Ln)Cl]Cl have been synthesized and thoroughly characterized. Under ambient conditions, both the complexes show excellent phenoxazinone synthase activity.
Topics & Concepts
ChemistryRedoxElectron paramagnetic resonanceAmine gas treatingATP synthaseCatalysisMetalStereochemistryCrystallographyMedicinal chemistryInorganic chemistryEnzymeOrganic chemistryNuclear magnetic resonancePhysicsMetal-Catalyzed Oxygenation MechanismsMetal complexes synthesis and propertiesFree Radicals and Antioxidants