Intense mid-infrared emission at 3.9 µm in Ho<sup>3+</sup>-doped ZBYA glasses for potential use as a fiber laser
Haiyan Zhao, Ruicong Wang, Xin Wang, Shijie Jia, Ya-Xian Fan, Elfed Lewis, Gerald Farrell, Shunbin Wang, Pengfei Wang
Abstract
Intense mid-infrared emission at 3.9 µm in <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:msup> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mi mathvariant="normal">H</mml:mi> <mml:mi mathvariant="normal">o</mml:mi> </mml:mrow> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mn>3</mml:mn> <mml:mo>+</mml:mo> </mml:mrow> </mml:msup> </mml:mrow> </mml:math> -doped ZBYA glasses with direct upper laser level ( <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:msup> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mi mathvariant="normal">H</mml:mi> <mml:mi mathvariant="normal">o</mml:mi> </mml:mrow> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mn>3</mml:mn> <mml:mo>+</mml:mo> </mml:mrow> </mml:msup> </mml:mrow> <mml:mo>:</mml:mo> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:msup> <mml:mi/> <mml:mn>5</mml:mn> </mml:msup> </mml:mrow> <mml:msub> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mi mathvariant="normal">I</mml:mi> </mml:mrow> <mml:mn>5</mml:mn> </mml:msub> </mml:math> ) pumping at a wavelength of 888 nm is reported for the first time, to the best of our knowledge. Spectroscopic parameters were determined using the Judd–Ofelt theory and the measured absorption spectrum. The maximum emission cross section of the <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:msup> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mi mathvariant="normal">H</mml:mi> <mml:mi mathvariant="normal">o</mml:mi> </mml:mrow> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mn>3</mml:mn> <mml:mo>+</mml:mo> </mml:mrow> </mml:msup> </mml:mrow> </mml:math> -doped ZBYA glass is estimated to be <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"> <mml:mn>2.7</mml:mn> <mml:mo>×</mml:mo> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:msup> <mml:mn>10</mml:mn> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mo>−</mml:mo> <mml:mn>21</mml:mn> </mml:mrow> </mml:msup> </mml:mrow> <mml:mspace width="thickmathspace"/> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:msup> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mi mathvariant="normal">c</mml:mi> <mml:mi mathvariant="normal">m</mml:mi> </mml:mrow> <mml:mn>2</mml:mn> </mml:msup> </mml:mrow> </mml:math> at 3906 nm. Additionally, fluorescence spectra and lifetimes of ZBYA glasses with different <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:msup> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mi mathvariant="normal">H</mml:mi> <mml:mi mathvariant="normal">o</mml:mi> </mml:mrow> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mn>3</mml:mn> <mml:mo>+</mml:mo> </mml:mrow> </mml:msup> </mml:mrow> </mml:math> ion doping concentrations were measured. The results provide theoretical and experimental basis for better selection of rare-earth-doped matrix glasses to achieve a fluorescence output centered on a wavelength of 3.9 µm.