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A comparison study of the efficacy of different activated charcoals derived from Palmyra kernel shell in removing phenolic compounds

Ganeshalingm Sashikesh, Periyasamy Anushkkaran, Yadhavan Praveena, Arumukham Manjceevan, Velauthamurty Kugamoorthy, Vignarooban Kandasamy

2023Current Research in Green and Sustainable Chemistry15 citationsDOIOpen Access PDF

Abstract

Phenol is one of the most prevalent contaminants discovered in water bodies. The adsorption process is gaining popularity as a viable method of removing phenolic chemicals from contaminated aquatic resources. The elimination of phenolic chemicals using Palmyra kernel shell activated charcoal has been extensively investigated. The removal effectiveness of Palmyra kernel shell charcoal was calculated using physically, chemically (H3PO4 and NaOH) and magnetically activated Palmyra kernel shell charcoal for various amounts of phenolic components and varying adsorption durations. According to this research study, physically activated charcoal has a much higher removal efficiency than other activated charcoal. These findings show that physically activated charcoal is easily used to remove phenolic compounds from polluted water resources. Adsorption kinetics were discovered to follow a pseudo-second-order kinetic model. Freundlich, Langmuir, and Temkin isotherm models were used to interpret the experimental results. Several kinetic formulas were utilized to evaluate the adsorption kinetics of phenolic compounds using various activated charcoals derived from Palmyra kernel shells. The experimental results are consistent with the Freundlich isotherm model. All of the activated and non-activated Palmyra kernel shells absorbed the phenolic chemicals, and the value of 1/n was found to be between 0.692 to 0.869. Scanning Electron Microscopy (SEM) is a technique used to characterize the surface morphology of adsorbents before and after adsorption. FTIR analyses confirmed the presence of phenolic compound functional groups on the adsorbents.

Topics & Concepts

AdsorptionFreundlich equationActivated carbonActivated charcoalLangmuirCharcoalPhenolPalm kernelNuclear chemistryChemistryShell (structure)Fourier transform infrared spectroscopyKineticsKernel (algebra)ChromatographyChemical engineeringMaterials scienceOrganic chemistryMathematicsFood scienceComposite materialPhysicsCombinatoricsPalm oilQuantum mechanicsEngineeringAdsorption and biosorption for pollutant removal