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Electrochemical oxidative cyclization of alkenes, boronic acids, and dichalcogenides to access chalcogenated boronic esters and 1,3-diols

Changfeng Huang, Jijing Hu, Guangxian Chen, Minjian Wu, Hua Cao, Xiang Liu

2021Organic Chemistry Frontiers21 citationsDOI

Abstract

A sustainable, environmentally benign electrochemical oxidative three-component cyclization of allylic alcohols, boronic acids, and dichalcogenides under metal-free and oxidant-free conditions has been developed.

Topics & Concepts

ChemistryAllylic rearrangementBoronic acidElectrochemistryOxidative phosphorylationOrganic chemistryCombinatorial chemistryCatalysisElectrodeBiochemistryPhysical chemistrySulfur-Based Synthesis TechniquesRadical Photochemical ReactionsCatalytic C–H Functionalization Methods
Electrochemical oxidative cyclization of alkenes, boronic acids, and dichalcogenides to access chalcogenated boronic esters and 1,3-diols | Litcius