Preparation of Sodium Lignosulfonate/Chitosan Adsorbent and Application of Pb2+ Treatment in Water
Jie Pan, Jiangwei Zhu, Fulong Cheng
Abstract
Industrial wastewater has brought huge disasters to water resources and soil and has seriously affected the growth of animals and plants. There is an urgent need for a green and efficient adsorbent to solve the problem of water pollution. Sodium lignosulfonate and chitosan undergo free radical polymerization to form a lignin/chitosan adsorbent, which is used to treat Pb2+ in water pollution. An orthogonal experiment was used to optimize the content of sodium lignosulfonate, chitosan, cross-linking agent and initiator to obtain the adsorbent with the best adsorption performance. The adsorbents were characterized by Fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), thermal analysis and zeta potentiometry. The influence of different conditions on the adsorption of heavy metal ions by lignosulfonate/chitosan adsorbent was explored, and a kinetic and isotherm model was established. The results showed that the adsorption capacity of Pb2+ was 345 mg g−1 when the adsorbent was 0.01 g, the concentration of heavy metal ions was 100 mg L−1 and pH was 7. The adsorption process of lignosulfonate/chitosan is a kind of spontaneous adsorption mode, which is mainly composed of electrostatic adsorption and chemical adsorption.