Fast divalent conduction in MB<sub>12</sub>H<sub>12</sub>·12H<sub>2</sub>O (M = Zn, Mg) complex hydrides: effects of rapid crystal water exchange and application for solid-state electrolytes
Kazuaki Kisu, Arunkumar Dorai, Sangryun Kim, Riku Hamada, Akichika Kumatani, Yoshiko Horiguchi, Ryuhei Sato, Kartik Sau, Shigeyuki Takagi, Shin‐ichi Orimo
Abstract
Water molecules are exchanged in the crystal structure, which imparts a high divalent conductivity to hydrated complex hydrides. MB 12 H 12 ·12H 2 O (M = Zn or Mg) exhibits exceptional conductivities higher than those of less-hydrated complex hydrides.
Topics & Concepts
DivalentConductivityCrystal structureMoleculeCrystallographyCrystal (programming language)Divalent metalInorganic chemistryChemistryElectrical resistivity and conductivityMaterials scienceAnalytical Chemistry (journal)Physical chemistryMetalPhysicsComputer scienceQuantum mechanicsOrganic chemistryProgramming languageChromatographyAdvanced Battery Materials and TechnologiesHydrogen Storage and MaterialsAdvanced NMR Techniques and Applications