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Kinetics and mechanisms of polycondensation reactions between aryl halides and bisphenol A

Yi Yang, Christopher L. Muhich, Matthew Green

2020Polymer Chemistry15 citationsDOIOpen Access PDF

Abstract

Computational and experimental verification of a second-order rate expression for polysulfones synthesized using diphenyldichloro sulfone <italic>versus</italic> a third-order rate expression for polysulfones synthesized using diphenyldifluoro sulfone.

Topics & Concepts

SulfoneCondensation polymerArylPolymer chemistryBisphenol AKineticsHalideChemistryMaterials scienceOrganic chemistryPolymerAlkylEpoxyPhysicsQuantum mechanicsOrganic and Inorganic Chemical ReactionsSynthesis and properties of polymersChemical Reaction Mechanisms
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