Using internal electrostatic fields to manipulate the valence manifolds of copper complexes
Alexander B. Weberg, Samuel P. McCollom, Laura M. Thierer, Michael R. Gau, Patrick J. Carroll, Neil C. Tomson
Abstract
Secondary coordination sphere electrostatic effects tune the valence manifolds of copper centers, impacting molecular geometries, photophysical properties, and redox potentials.
Topics & Concepts
Valence (chemistry)CopperRedoxChemical physicsChemistryElectrostaticsCoordination sphereElectrostatic interactionComputational chemistryIonCrystallographyInorganic chemistryPhysical chemistryOrganic chemistryElectrochemical Analysis and ApplicationsIonic liquids properties and applicationsSurface Chemistry and Catalysis