Palladium-catalyzed direct reductive cross-coupling of aryltrimethylammonium salts with aryl bromides
Chen Zhang, Nana Ma, Zi-Lun Yu, Chuanji Shen, Xiaocong Zhou, Xue‐Qiang Chu, Weidong Rao, Zhi‐Liang Shen
Abstract
Palladium-catalyzed direct reductive cross-coupling of aryltrimethylammonium salts with aryl bromides proceeded efficiently in a one-pot manner in the presence of Mg turnings, LiCl, and TMEDA in THF to afford the corresponding biaryl compounds.
Topics & Concepts
ChemistryPalladiumArylCatalysisCoupling (piping)Combinatorial chemistryPolymer chemistryOrganic chemistryMetallurgyAlkylMaterials scienceCatalytic C–H Functionalization MethodsCatalytic Cross-Coupling ReactionsRadical Photochemical Reactions