Visible-light-induced indole synthesis <i>via</i> intramolecular C–N bond formation: desulfonylative C(sp<sup>2</sup>)–H functionalization
Quan‐Zhe Li, Xin-Tao Gu, Yin Wei, Min Shi
Abstract
-substituted indoles with a broad scope through γ-fragmentation under mild conditions in the absence of any additional additive. The reaction mechanism paradigm has been investigated on the basis of deuterium labeling experiments, kinetic analysis, Hammett plotting analysis and DFT calculations.
Topics & Concepts
Indole testSurface modificationChemistryIntramolecular forceDeuteriumPhotochemistryReaction mechanismCombinatorial chemistryFragmentation (computing)RedoxComputational chemistryOrganic chemistryCatalysisPhysical chemistryPhysicsOperating systemQuantum mechanicsComputer scienceCatalytic C–H Functionalization MethodsRadical Photochemical ReactionsSulfur-Based Synthesis Techniques