Palladium-catalyzed synthesis of benzosilacyclobutenes<i>via</i>position-selective C(sp<sup>3</sup>)–H arylation
Naoya Hamada, Daigo Hayashi, Ryo Shintani
Abstract
)-H bond activation, including those having substituents at the methylene carbon on the 4-membered silacycle. The obtained products could be engaged in the palladium- or nickel-catalyzed ring-expansion reactions to give compounds possessing 6-membered silacycles.
Topics & Concepts
CatalysisPalladiumChemistryPosition (finance)Combinatorial chemistryMedicinal chemistryOrganic chemistryFinanceEconomicsCatalytic C–H Functionalization MethodsCatalytic Cross-Coupling ReactionsRadical Photochemical Reactions