A series of four novel alkaline earth metal–organic frameworks constructed of Ca(<scp>ii</scp>), Sr(<scp>ii</scp>), Ba(<scp>ii</scp>) ions and tetrahedral MTB linker: structural diversity, stability study and low/high-pressure gas adsorption properties
Miroslav Almáši, Vladimı́r Zeleňák, Róbert Gyepes, Ľuboš Zauška, Sandrine Bourrelly
Abstract
Four novel microporous alkaline earth metal–organic frameworks (AE-MOFs) containing methanetetrabenzoate linker (MTB): <bold>UPJS-6</bold>, <bold>UPJS-7</bold>, <bold>UPJS-8</bold> and <bold>UPJS-9</bold> have been successfully prepared, characterized and tested as adsorbents for different gases.
Topics & Concepts
Alkaline earth metalLinkerSeries (stratigraphy)ChemistryIonTetrahedronLanthanideMetal ions in aqueous solutionAlkali metalStability (learning theory)CrystallographyStereochemistryGeologyOrganic chemistryComputer scienceOperating systemPaleontologyMachine learningMetal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesLanthanide and Transition Metal Complexes