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Tetrafluoroborate-Monofluorophosphate (NH<sub>4</sub>)<sub>3</sub>[PO<sub>3</sub>F][BF<sub>4</sub>]: First Member of Oxyfluoride with B–F and P–F Bonds

Haotian Qiu, Wenbing Cai, Zhihua Yang, Yanli Liu, Miriding Mutailipu, Shilie Pan

2021ACS Organic & Inorganic Au16 citationsDOIOpen Access PDF

Abstract

] were confirmed by several approaches, including single-crystal structure analysis; bond valence analysis; and X-ray energy dispersive, infrared spectrum, and also nuclear magnetic resonance spectroscopy. This work is of great significance to enrich the solid-state chemistry of borates and phosphates and also open a new branch of mixed anion compound with fluoroborate-fluorophosphates.

Topics & Concepts

FluorineTetrafluoroborateBoronChemistryFluorideValence (chemistry)Infrared spectroscopyInorganic chemistryAmmoniumCrystal chemistrySpectroscopyIonOxidation stateCrystallographyCrystal structureCatalysisOrganic chemistryPhysicsIonic liquidQuantum mechanicsInorganic Fluorides and Related CompoundsCrystal Structures and PropertiesChemical Synthesis and Characterization
Tetrafluoroborate-Monofluorophosphate (NH<sub>4</sub>)<sub>3</sub>[PO<sub>3</sub>F][BF<sub>4</sub>]: First Member of Oxyfluoride with B–F and P–F Bonds | Litcius