Solvent-mediated precipitating synthesis and optical properties of polyhydrido Cu<sub>13</sub>nanoclusters with four vertex-sharing tetrahedrons
Xinzhang Lin, Jie Tang, Chenyu Zhu, Li Wang, Yang Yang, Ren’an Wu, Hongjun Fan, Chao Liu, Jiahui Huang
Abstract
A solvent-mediated precipitating synthesis was developed to efficiently prepare novel high-purity Cu 13 H 10 (SR) 3 (PPh 3 ) 7 nanoclusters with an aesthetic crystal structure, unique optical properties and ultrafast relaxation dynamics.
Topics & Concepts
NanoclustersTetrahedronVertex (graph theory)SolventChemistryMaterials scienceCrystallographyNanotechnologyChemical physicsCombinatoricsMathematicsOrganic chemistryGraphNanocluster Synthesis and ApplicationsGold and Silver Nanoparticles Synthesis and ApplicationsCopper-based nanomaterials and applications