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Greatly enhanced tunneling electroresistance in ferroelectric tunnel junctions with a double barrier design

Wei Xiao, Xiaohong Zheng, Hua Hao, Lili Kang, Lei Zhang, Zhi Zeng

2023npj Computational Materials18 citationsDOIOpen Access PDF

Abstract

Abstract We propose that the double barrier effect is expected to enhance the tunneling electroresistance (TER) in the ferroelectric tunnel junctions (FTJs). To demonstrate the feasibility of this mechanism, we design a model structure of Pt/BaTiO 3 /LaAlO 3 /Pt/BaTiO 3 /LaAlO 3 /Pt double barrier ferroelectric tunnel junction (DB-FTJ), which can be considered as two identical Pt/BaTiO 3 /LaAlO 3 /Pt single barrier ferroelectric tunnel junctions (SB-FTJs) connected in series. Based on density functional calculation, we obtain the giant TER ratio of 2.210 × 10 8 % in the DB-FTJ, which is at least three orders of magnitude larger than that of the SB-FTJs of Pt/BaTiO 3 /LaAlO 3 /Pt, together with an ultra-low resistance area product (0.093 KΩμm 2 ) in the high conductance state of the DB-FTJ. Moreover, it is possible to control the direction of polarization of the two single ferroelectric barriers separately and thus four resistance states can be achieved, making DB-FTJs promising as multi-state memory devices.

Topics & Concepts

FerroelectricityQuantum tunnellingMaterials scienceTunnel junctionCondensed matter physicsPolarization (electrochemistry)ConductanceNanotechnologyOptoelectronicsPhysicsChemistryDielectricPhysical chemistryFerroelectric and Piezoelectric MaterialsElectronic and Structural Properties of OxidesFerroelectric and Negative Capacitance Devices
Greatly enhanced tunneling electroresistance in ferroelectric tunnel junctions with a double barrier design | Litcius