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Pd-Catalyzed Oxidative Dehydrogenative Cross Coupling of Cage B–H/B–H Bonds at Room Temperature: Synthesis of Bis(<i>o</i>-carborane)s

Donghong Luo, Yatong Fu, Ju‐You Lu

2022Inorganic Chemistry16 citationsDOI

Abstract

Efficient Pd-catalyzed oxidative dehydrogenative cross coupling of B–H/B–H bonds of two pyridyl o-carboranes has been developed, leading to the preparation of B(3)–B(6′) heterocoupled and B(3)–B(6′) homocoupled biscarboranes with a broad substrate scope at room temperature.

Topics & Concepts

ChemistryCageCarboraneCatalysisSubstrate (aquarium)Oxidative phosphorylationCoupling (piping)Scope (computer science)Oxidative coupling of methaneMedicinal chemistryStereochemistryPolymer chemistryOrganic chemistryMetallurgyMathematicsBiochemistryProgramming languageComputer scienceOceanographyCombinatoricsMaterials scienceGeologyBoron Compounds in ChemistryMedical Imaging Techniques and ApplicationsRadiopharmaceutical Chemistry and Applications
Pd-Catalyzed Oxidative Dehydrogenative Cross Coupling of Cage B–H/B–H Bonds at Room Temperature: Synthesis of Bis(<i>o</i>-carborane)s | Litcius