The Giese reaction of alkyl bromides using amine carboxyboranes
Changhee Park, Seyun Gi, Seongkyeong Yoon, Seong Jung Kwon, Sunggi Lee
Abstract
The Giese reaction of alkyl bromides was achieved using amine carboxyboranes as ligated boryl radical precursors. Furthermore, ligated boryl radicals were utilized to establish carbon–boron bonds.
Topics & Concepts
ChemistryAlkylAmine gas treatingHalogenMedicinal chemistryCombinatorial chemistryPolymer chemistryOrganic chemistryPlant-based Medicinal ResearchAsymmetric Synthesis and CatalysisChemical Reactions and Isotopes