Itinerant metamagnetic transition in the ferromagnet <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:mrow><mml:mi>LuC</mml:mi><mml:msub><mml:mi mathvariant="normal">o</mml:mi><mml:mn>3</mml:mn></mml:msub></mml:mrow></mml:math> induced by high field: Instability of the <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:mrow><mml:mn>3</mml:mn><mml:mi>d</mml:mi></mml:mrow></mml:math>-electron subsystem
D. S. Neznakhin, D. I. Radzivonchik, D. I. Gorbunov, А. В. Андреев, J. Šebek, A. V. Lukoyanov, M.I. Bartashevich
Abstract
$\mathrm{LuC}{\mathrm{o}}_{3}$ is an itinerant ferromagnet whose magnetic properties strongly depend on the position of the $3d$ electronic states relative to the Fermi level. Here, we report on the magnetization of a $\mathrm{LuC}{\mathrm{o}}_{3}$ single crystal in pulsed magnetic fields up to 58 T. We find a field-induced phase transition just below 50 T from a low-spin to a high-spin state. The transition shows a pronounced anisotropy of the magnetization jump and hysteresis. A series of ab initio calculations based on the density functional theory show that the transition is due to a significant change in the occupancies of the Co $3d$ electronic states. At the same time, some features in the majority spin density of the Co $3d$ states are slightly modified and pass through the Fermi level when the spin state is changed, which leads to the instability of the $3d$-electron subsystem. Thereby, the applied magnetic field causes a significant redistribution in the majority and minority spin states in the Co $3d$ subsystem, which results in the sharp change in the magnetization.