Visible-light-induced Smiles rearrangement without release of SO<sub>2</sub>: rapid access to alkyl sulfonyl derivatives
Yunpeng Cao, Xinmou Wang, Haoran Jiao, Hongjian Song, Yuxiu Liu, Qingmin Wang
Abstract
Conventional visible-light-induced Smiles rearrangements generate C, N, or O radicals and release SO 2 .
Topics & Concepts
SulfonylSmiles rearrangementAlkylChemistryVisible spectrumPhotochemistryMedicinal chemistryCombinatorial chemistryOrganic chemistryMaterials scienceOptoelectronicsSulfur-Based Synthesis TechniquesRadical Photochemical ReactionsPhenothiazines and Benzothiazines Synthesis and Activities