Electromagnetic mill promoted mechanochemical palladium-catalyzed solid state cyanation of aryl bromides using non-toxic K<sub>4</sub>[Fe(CN)<sub>6</sub>]
Yanan Hou, Hui Wang, Juan Xi, Ruonan Jiang, Lizhi Zhang, Xinjin Li, Fenggang Sun, Qing Liu, Zengdian Zhao, Hui Liu
Abstract
We have developed the first electromagnetic mill (EMM) promoted mechanochemical palladium-catalyzed solid state cyanidation of aryl bromides using non-toxic K 4 [Fe(CN) 6 ] without additional heating.
Topics & Concepts
CyanationPalladiumArylCatalysisChemistrySolid-stateMillOrganic chemistryPhysical chemistryAlkylCatalytic Cross-Coupling ReactionsCatalytic C–H Functionalization MethodsSynthesis and Reactivity of Heterocycles