Preparation of Rechargeable Antibacterial Polypropylene/N-Halamine Materials Based on Melt Blending and Surface Segregation
Ge Zhang, Yuke Li, Qining Ke, Junchen Bai, Fushuai Luo, Jiacheng Zhang, Yanfen Ding, Juan Chen, Peng Liu, Shu Wang, Chong Gao, Mingshu Yang
Abstract
Polypropylene (PP) has been widely used in health care and food packaging fields, however, it lacks antibacterial properties. Herein, we prepared the polymeric antibacterial agents (MPP-NDAM) by an in situ amidation reaction between 2,4-diamino-6-dialkylamino-1,3,5-triazine (NDAM) and maleic anhydride grafted polypropylene (MPP) using the melt grafting method. The effects of reaction time and monomer content on the grafting degree of N-halamine were investigated, and a grafting degree of 4.86 wt % was achieved under the optimal reaction conditions. PP/MPP-NDAM composites were further obtained by a melt blending process between PP and MPP-NDAM. With the adoption of surface segregation technology, the content of N-halamine structure on the surface of PP/MPP-NDAM composites was significantly increased. The antibacterial tests showed that the PP/MPP-NDAM composite could achieve 99.9% bactericidal activity against 1.0 × 10 7 CFU/mL of Escherichia coli ( E. coli ) and Staphylococcus aureus ( S. aureus ) within 10 and 5 min of contact, respectively. The antibacterial effect became more pronounced with the prolongation of chlorinated time, and it could achieve 99.9% bactericidal activity against E. coli within merely 1 min of contact.