Electrochemical Redox Processes Involved in Carbon-Coated KVPO <sub>4</sub> F for High Voltage K-Ion Batteries Revealed by XPS Analysis
Laure Caracciolo, Lénaïc Madec, Emmanuel Petit, Vincent Gabaudan, Dany Carlier, Laurence Croguennec, Hervé Martinez
Abstract
K-ion batteries need efficient positive electrode materials with open structural frameworks to accommodate the large ionic radius of K + . In that direction, polyanionic compounds are of great interest. Among them, KVPO 4 F is the most studied one. Its electrochemical redox processes still remain unclear, especially at high voltage. To tackle this issue, X-ray photoelectron spectroscopy was used to reveal the electrochemical redox processes of K x VPO 4 F. First, a carbon coating was performed and allowed increasing the overall electrochemical performance while mitigating electrolyte degradation at high voltage. Then, XPS analysis showed a high reversibility of the redox processes although the K + extraction (and insertion) from x = 0.5 to 0 was hindered, possibly by structural constraints while electrolyte degradation occurred mostly above 4.5 V.