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Phosphate anion-induced silver-chalcogenide cluster-based metal organic frameworks as dual-functional catalysts for detoxifying chemical warfare agent simulants

Chunhua Gong, Zhi‐Bing Sun, Man Cao, Xi‐Ming Luo, Jie Wu, Qian‐You Wang, Shuang‐Quan Zang, Thomas C. W. Mak

2022Chemical Communications22 citationsDOI

Abstract

Two porphyrinic silver-chalcogenide cluster-based MOFs were achieved using a phosphate anionic template strategy, and the highly photoactive organic building modules combined with Lewis acidic silver clusters allow both SCC-MOFs to be used as versatile catalysts for the simultaneous degradation of sulfur mustard and nerve agent simulants.

Topics & Concepts

ChalcogenidePhosphateCatalysisDual (grammatical number)IonInorganic chemistryCluster (spacecraft)Metal ions in aqueous solutionChemistryMetal-organic frameworkCombinatorial chemistryMaterials scienceNanotechnologyOrganic chemistryAdsorptionComputer scienceProgramming languageArtLiteratureMetal-Organic Frameworks: Synthesis and ApplicationsAdvanced Nanomaterials in CatalysisNanocluster Synthesis and Applications
Phosphate anion-induced silver-chalcogenide cluster-based metal organic frameworks as dual-functional catalysts for detoxifying chemical warfare agent simulants | Litcius