Surface-Modification Strategy to Produce Highly Anticorrosive Ti3C2Tx MXene-Based Polymer Composite Coatings: A Mini-Review
Shufang Zhang, Guoqin Zhang, Liang Fang, Zhiheng Wang, Fang Wu, Gaobin Liu, Qirui Wang, Hongen Nian
Abstract
MXenes are a group of novel two-dimensional (2D) materials with merits such as large specific surface area, abundant surface-functional groups, high chemical activity, excellent mechanical properties, high hydrophilicity, and good compatibility with various polymers. In recent years, many novel high-performance organic anticorrosion coatings using MXenes as nanofillers have been reported and have attracted widespread attention. As the first successfully prepared MXene material, Ti3C2Tx is the most extensively studied and typical member of the MXene family. Therefore, it is taken as the representative of its family, and the status of Ti3C2Tx MXene/epoxy resin (EP) and MXene/waterborne polyurethane (WPU) polymer anticorrosive composite coatings is reviewed. Firstly, the structure, characteristics, and main synthesis methods of MXenes are briefly introduced. Then, the latest progress of four surface-modification strategies to improve the dispersion, compatibility, stability, and anti-aggregation properties of MXenes, namely functionalization grafting, orientation regulation, heterostructure nanocomposite design, and stabilization and greening treatment, are analyzed and summarized. Finally, the current challenges and future opportunities regarding MXene-based corrosion-resistant organic composite coatings are discussed prospectively.