The role of molecular fluorophores in the photoluminescence of carbon dots derived from citric acid: current state-of-the-art and future perspectives
Wiktor Kasprzyk, Tomasz Świergosz, Piotr P. Romańczyk, Jochen Feldmann, Jacek K. Stolarczyk
Abstract
a bottom-up approach, molecular fluorophores are considered to dominate the optical characteristics of the resulting nanomaterials. In this review, the recent progress in the use of molecular state theory for explanation of the structure-property relationship in CDs is summarized. This review focuses exclusively on the molecular fluorophores existing in nanomaterials prepared from citric acid (CA) as one of the most frequent carbon sources reported for the bottom-up synthesis of CDs. Consequently, the most relevant transformations of CA and the history of molecular fluorophores derived from it are described, followed by an in-depth discussion on their relevance in understanding the specific photophysical properties of blue-, green-, and red-emitting CDs. Finally, the challenging issues and future perspectives of molecular state PL mechanism exploration in CDs are highlighted.