Mechanistic studies on single-electron transfer in frustrated Lewis pairs and its application to main-group chemistry
Lars J. C. van der Zee, J. Hofman, Joost M. van Gaalen, J. Chris Slootweg
Abstract
N and TCNQ. Finally, an analysis of sulfonium salts as electron acceptors will demonstrate how to manage systems with rapidly decomposing radical species. This framework equips the reader with an expanded array of tools for both predicting and characterizing SET events within FLP chemistry, thereby enabling its extension and application to the broader domain of main-group (photo)redox chemistry.
Topics & Concepts
Frustrated Lewis pairChemistryGroup (periodic table)Electron transferLewis acids and basesNanotechnologyCombinatorial chemistryPhotochemistryOrganic chemistryCatalysisMaterials scienceOrganoboron and organosilicon chemistrySynthesis and characterization of novel inorganic/organometallic compoundsCrystallography and molecular interactions