Sustainable and Efficient Low‐Energy Light Emitters: A Series of One‐Dimensional d<sup>10</sup> Coinage Metal–Organic Chalcogenolates, [M(<i>o</i>‐SPhCO<sub>2</sub>H)]<sub>n</sub>
Oleksandra Veselska, Nathalie Guillou, Maria Diaz‐Lopez, P. Bordet, Gilles Ledoux, Sébastien Lebègue∥, Adel Mesbah, Alexandra Fateeva, Aude Demessence
Abstract
Abstract A series of d 10 coinage metal thiosalicylate coordination polymers (CPs) is reported. The 1D structures of the three CPs are formed by M 3 S 3 fused hexagons for Cu and Ag compounds and interpenetrated helical chains for Au CP. Depending on the metal, solid‐state red and NIR emissive CPs are obtained with quantum yields up to 50 %, providing a great opportunity to replace the actual emissive critical raw materials.
Topics & Concepts
MetalPolymerSeries (stratigraphy)Materials scienceSolid-stateRaw materialSustainable energyCrystallographyNanotechnologyChemistryPhysical chemistryMetallurgyOrganic chemistryComposite materialElectrical engineeringBiologyEngineeringRenewable energyPaleontologyMetal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesNanocluster Synthesis and Applications