Dess-Martin Periodinane (DMP) in Organic Synthesis-A Septennial Update (2015-tillDate)
Ravi Varala, Vittal Seema, Mohammed Mujahid Alam, Mohammed Mujahid Alam, Mohammed Amanullah, Narsimhaswamy Dubasi
Abstract
Abstract: Dess-Martin periodinane (DMP) is one of the hypervalent iodines that is most frequently utilized as an oxidizing agent in organic chemistry. The authors of this septennial review have critically and methodically presented representative applications of DMP in organic synthesis from 2015 to the present, including oxidations, dehydrogenations, hetero and homo-dimerizations, aromatizations, thiocyanations, halogenations, dearylations, ring expansions, cyclizations, heterocyclic ring formation, and other miscellaneous reactions. This review discusses the range and constraints of these transformations.
Topics & Concepts
ChemistryHypervalent moleculeOxidizing agentRing (chemistry)Organic chemistryCombinatorial chemistryOrganic synthesisCatalysisReagentOxidative Organic Chemistry ReactionsSynthesis and Catalytic ReactionsChemical Synthesis and Reactions