The azidosulfonylation of terminal alkynes leading to β-azidovinyl sulfones
Long Zheng, Zhanjing Wang, Chen Li, Yong Wu, Zhaohong Liu, Yongquan Ning
Abstract
We report herein the first example of the N 3 radical-mediated azidosulfonylation of alkynes, affording the β-azidovinyl sulfone products with a broad substrate scope, excellent functional group compatibility, and high yield.
Topics & Concepts
SulfoneCompatibility (geochemistry)Terminal (telecommunication)Yield (engineering)ChemistrySubstrate (aquarium)Scope (computer science)Functional groupCombinatorial chemistryOrganic chemistryMaterials scienceComputer scienceBiologyProgramming languageEcologyPolymerTelecommunicationsComposite materialMetallurgySulfur-Based Synthesis TechniquesRadical Photochemical ReactionsCatalytic C–H Functionalization Methods