Visible light-induced<i>gem</i>-difluoroallylation of [1.1.1]propellane to access<i>gem</i>-difluoroallylic bicyclo[1.1.1]pentanes
Hui Zhu, Shengxing Wu, Bingbin Zhu, Jiacheng Li, Deyou Lan, Wenhao Xu, Gongcheng Xu, Yu Zhu, Chuanming Yu, Xinpeng Jiang
Abstract
-difluoroallylic bicyclo[1.1.1]pentanes. Importantly, our methodology is characterized by mild reaction conditions, wide reactant scope, and suitable functional group tolerance.
Topics & Concepts
PropellaneBicyclic moleculeChemistryComputational chemistryPhotochemistryStereochemistryFluorine in Organic ChemistryRadical Photochemical ReactionsInorganic Fluorides and Related Compounds