Quasi‐1D van der Waals Antiferromagnetic CrZr<sub>4</sub>Te<sub>14</sub> with Large In‐Plane Anisotropic Negative Magnetoresistance
Yuqiang Fang, Ke Yang, Enze Zhang, Shanshan Liu, Zehao Jia, Yuda Zhang, Hua Wu, Faxian Xiu, Fuqiang Huang
Abstract
Abstract The discovery of 2D van der Waals (vdW) magnetic materials is of great significance to explore intriguing 2D magnetic physics and develop innovative spintronic devices. In this work, a new quasi‐1D vdW layered compound CrZr 4 Te 14 is successfully synthesized. Owing to the existence of 1D [CrTe 2 ] and [ZrTe 3 ] chains along the b ‐axis, CrZr 4 Te 14 crystals show strong anisotropy of phonon vibrations, electrical transport, and magnetism. Density functional theory calculations reveal the ferromagnetic (FM) coupling within the [CrTe 2 ] chain, while the interchain and interlayer couplings are both weakly antiferromagnetic (AF). Notably, a large intrinsic negative magnetoresistance (nMR) of −56% is achieved at 2 K under 9 T, and the in‐plane anisotropic factor of nMR can reach up to 8.2 in the CrZr 4 Te 14 device. The 1D FM chains and anisotropic nMR effect make CrZr 4 Te 14 an interesting platform for exploring novel polarization‐sensitive spintronics.