Co‐based Catalysts for Selective H<sub>2</sub>O<sub>2</sub> Electroproduction via 2‐electron Oxygen Reduction Reaction
Ruixue Zheng, Qinglei Meng, Li Zhang, Junjie Ge, Changpeng Liu, Wei Xing, Meiling Xiao
Abstract
Abstract Electrochemical production of hydrogen peroxide (H 2 O 2 ) via two‐electron oxygen reduction reaction (ORR) process is emerging as a promising alternative method to the conventional anthraquinone process. To realize high‐efficiency H 2 O 2 electrosynthesis, robust and low cost electrocatalysts have been intensively pursued, among which Co−based catalysts attract particular research interests due to the earth‐abundance and high selectivity. Here, we provide a comprehensive review on the advancement of Co−based electrocatalyst for H 2 O 2 electroproduction. The fundamental chemistry of 2‐electron ORR is discussed firstly for guiding the rational design of electrocatalysts. Subsequently, the development of Co−based electrocatalysts involving nanoparticles, compounds and single atom catalysts is summarized with the focus on active site identification, structure regulation and mechanism understanding. Moreover, the current challenges and future directions of the Co−based electrocatalysts are briefly summarized in this review.