A micro-environment tuning approach for enhancing the catalytic capabilities of lanthanide containing polyoxometalate in the cyanosilylation of ketones
Yanmei Nie, Sang-Hao Li, Ming‐Yuan Lin, Jun Yan
Abstract
The as-synthesized (TBA)8H5[Nd(SiW11O39)2] manifested high catalytic activity for cyanosilylation of ketones, and its catalytic activity could be improved further through rational design of the reaction micro-environment beyond the molecular level, and the corresponding mechanism has been systematically studied.
Topics & Concepts
PolyoxometalateLanthanideCatalysisMaterials scienceCombinatorial chemistryChemistryNanotechnologyOrganic chemistryIonPolyoxometalates: Synthesis and ApplicationsChemical Synthesis and ReactionsOxidative Organic Chemistry Reactions