Preferential adsorption of ethane over ethylene on a Zr-based metal–organic framework: impacts of C–H⋯N hydrogen bonding
Yaping Zhang, Daofei Lv, Jiayu Chen, Zewei Liu, Chongxiong Duan, Xin Chen, Wenbing Yuan, Hongxia Xi, Qibin Xia
Abstract
C–H⋯N interactions are more important than C–H⋯π interactions for ethane-selective adsorption.
Topics & Concepts
ChemistryAdsorptionEthyleneHydrogen bondMetal-organic frameworkMetalHydrogenInorganic chemistryOrganic chemistryMoleculeCatalysisMetal-Organic Frameworks: Synthesis and ApplicationsCovalent Organic Framework ApplicationsCrystallography and molecular interactions