Design of Fluorescence Enhancing Sensor for Mercury Detection via Bamboo Cellulose-Derived Carbon Dots
V Bavya, T.P.D. Rajan, Kattimuttathu I. Suresh
Abstract
Mercury contamination of the environment is extremely hazardous to human health because of its significant toxicity, especially in water. Biomass-derived fluorophores such as carbon dots (CDs) have emerged as eco-friendly and cost-effective alternative sensors that provide comparable efficacy while mitigating the environmental and economic drawbacks of conventional methods. In this work, we report the fabrication of a selective fluorescence-enhancing sensor based on sulfur-doped carbon dots (SCDs) using waste bamboo-derived cellulose and sodium thiosulfate as the soft base dopant, which actively complexes with mercury ions for detection. SCDs with an average size of 4 nm were synthesized hydrothermally, and the sulfur doping was confirmed quantitatively with an atomic percentage of 6.5%. Optical studies reveal an abnormal fluorescence enhancement of SCD in the presence of mercury due to the aggregation of carbon dots via sulfur-containing functional groups. The fabricated sensor exhibits a low detection limit of 5.16 nM, suggesting its application potential as a reliable mercury sensor. Real-time analyses carried out using tap water samples spiked with mercury and industry samples showed high efficiency for Hg(II) detection. The sensing performance was also demonstrated by using SCD-coated filter paper strips.