Thermal decomposition of ammonium perchlorate-based molecular perovskite from TG-DSC-FTIR-MS and <i>ab initio</i> molecular dynamics
Pengfei Zhai, Chengying Shi, Shengxiang Zhao, Wenbin Liu, Wenxin Wang, Lina Yao
Abstract
Organic components realize a more efficient autocatalytic chain propagation for degradation of ClO<sub>4</sub><sup>−</sup> in the thermal decomposition process of DAP.
Topics & Concepts
Ammonium perchlorateChemistryFourier transform infrared spectroscopyDifferential scanning calorimetryThermogravimetric analysisThermal decompositionPhysical chemistryDABCOInfrared spectroscopyOctaneChemical engineeringOrganic chemistryThermodynamicsEngineeringPhysicsEnergetic Materials and CombustionThermal and Kinetic AnalysisChemical Thermodynamics and Molecular Structure