Preparation of a Chitosan-Lead Composite Carbon Aerogel and Its Catalytic Thermal Decomposition Performance on Ammonium Perchlorate
Yujie Yan, Bo Jin, Qian Zhou, Jinhao Zhang, Rufang Peng
Abstract
Chitosan-lead (CS-Pb) carbon aerogels were prepared by ionic cross-linking and high-temperature carbonization using chitosan (CS) as the carbon precursor. The obtained carbon aerogels were characterized by scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FT-IR), X-ray diffractometry (XRD), and X-ray photoelectron spectroscopy (XPS). The obtained aerogels have a 3D structure and a large surface area, which can effectively prevent the agglomeration phenomenon of metals. Differential thermal analysis (DTA) was used to analyze the catalytic performance of a carbon aerogel for ammonium perchlorate (AP). The results showed that the CS-Pb carbon aerogel reduced the peak temperature of AP pyrolysis from 703.9 to 627.7 K. According to the Kissinger method calculations, the Ea of AP decomposition decreased about 27.2 kJ/mol. The TG data at different warming rates were analyzed by the Flynne–Walle–Ozawa (FWO) and Kissinger–Akahira–Sunose (KAS) methods, which are two of the isoconversion methods, and the activation energies of AP and AP+CS-Pb-3.5 were calculated. Between the conversion degrees (α) of 0.1 and 0.9, the Ea values obtained by the two isoconversion methods are similar and have a certain match. Also, the two isoconversion methods confirm Kissinger’s calculation. Finally, thermogravimetry-mass spectrometry (TG-MS) was used to monitor the gases generated during the thermal decomposition of the AP+CS-Pb-3.5 system in real time.