Structurally characterised intermediate of the oxidative addition of a heteroleptic germylene to gallanediyle
Anna Bücker, Christoph Wölper, Gebhard Haberhauer, Stephan Schulz
Abstract
) yielded LGa(μ-Cl)GeDMP (2), which represents an intermediate of the oxidative addition reaction. 1-3 were characterized by NMR and IR spectroscopy as well as by single crystal X-ray diffraction (sc-XRD), while their electronic nature was analyzed by quantum chemical calculations.
Topics & Concepts
Oxidative additionChemistryAcceptorCrystallographyMetalSingle crystalQuantum chemicalOxidative phosphorylationCrystal structureMedicinal chemistryPhotochemistryStereochemistryMoleculeCatalysisOrganic chemistryPhysicsCondensed matter physicsBiochemistrySynthesis and characterization of novel inorganic/organometallic compoundsOrganoboron and organosilicon chemistryCoordination Chemistry and Organometallics