Efficacious removal of mercury metal in food industry sewerage utilizing reduced graphene oxide adsorbent composited with magnetic nanoparticles
Adel Beig Babaei, Arash Dara, Hossein Taheri
Abstract
• Graphene oxide nanoparticles used to their absorptivity and high specific surface area. • magnetized oxide nanographene adsorbent containing iron nanoparticles was used to remove mercury from environment. • maximum efficiency of mercury absorption by magnetized nanographene oxide occurred at a pH of 6. • graphene oxide magnetized with iron nanoparticles can be effectively used to remove mercury from wastewater. • Nanographene oxide with high surface area, hydrophobicity, negative charge used as an effective adsorbent for removing metals. This study examines the effectiveness of a composite material made from reduced graphene oxide (rGO) and magnetic nanoparticles for the adsorption of heavy metals from wastewater, addressing a critical environmental issue as heavy metal pollution poses significant risks to human health. Traditional water treatment methods often fail to adequately remove these persistent contaminants. The composite takes advantage of graphene's high surface area and adsorption capacity, while the magnetic nanoparticles facilitate easy separation and reusability of the adsorbent. Characterization techniques such as X-ray diffraction (XRD) and Raman spectroscopy were employed to confirm the composite's structural integrity and the presence of rGO, highlighting its functional properties. The study's focus lay on investigating mercury removal efficiency across varying pH levels (1-6), temperatures (25°C), mercury concentrations (10 g/L), adsorbent amounts (0.01-0.05 g/L), and contact times (120-360 seconds). The findings indicated that optimal mercury adsorption occurred at pH 6, with a 100 seconds contact time, 25°C, and 0.05 g of adsorbent. The maximum mercury removal achieved was quantified at 9.15 µg/L, demonstrating the potential of iron nanoparticle-magnetized nano graphene oxide as an efficient and sustainable solution for heavy metal remediation in wastewater treatment applications. The results obtained showed that graphene oxide magnetized with iron nanoparticles can be effectively used to remove mercury from water and wastewater samples.Overall, this research highlights a promising pathway towards addressing the pressing challenge of water pollution with heavy metals.