Thermosalience coupled to abrupt spin crossover with dynamic ligand motion in an iron(<scp>ii</scp>) molecular crystal
Hiroaki Hagiwara, Souta Konomura
Abstract
Thermally induced dynamic ligand motion of a newly synthesized iron( ii ) molecular crystal induces unusual thermosalient effects coupled to spin crossover and a symmetry change.
Topics & Concepts
Spin crossoverLigand (biochemistry)Crystal (programming language)CrossoverSymmetry (geometry)Molecular dynamicsMotion (physics)Spin (aerodynamics)Materials scienceChemical physicsChemistryCrystallographyPhysicsComputational chemistryClassical mechanicsReceptorThermodynamicsGeometryComputer scienceMathematicsBiochemistryArtificial intelligenceProgramming languageMagnetism in coordination complexesPorphyrin and Phthalocyanine ChemistryMetal-Catalyzed Oxygenation Mechanisms