A trinuclear metallasilsesquioxane of uranium(<scp>iii</scp>)
Maxime Tricoire, Nadir Jori, Farzaneh Fadaei‐Tirani, Rosario Scopelliti, Ivica Živković, Louise S. Natrajan, Marinella Mazzanti
Abstract
The silsesquioxane ligand ( iBu POSSH 3 ) allowed the assembly of robust polynuclear complexes of uranium( iii ) and the isolation of the first trinuclear U( iii ) complex that exhibits magnetic exchange.
Topics & Concepts
SilsesquioxaneUraniumChemistryLigand (biochemistry)Reduction (mathematics)Combinatorial chemistryIsolation (microbiology)Reducing agentCrystallographyOrganic chemistryMaterials scienceBioinformaticsReceptorBiochemistryBiologyPolymerMetallurgyMathematicsGeometryMagnetism in coordination complexesLanthanide and Transition Metal ComplexesInorganic Chemistry and Materials