Engineering macrocyclic high performance pentagonal bipyramidal Dy( <scp>iii</scp> ) single-ion magnets
Angelos B. Canaj, Sourav Dey, Claire Wilson, Oscar Céspedes, Gopalan Rajaraman, Mark Murrie
Abstract
We highlight the vast synthetic scope for macrocyclic engineering of magnetic anisotropy, generating a high performance pentagonal bipyramidal Dy( <sc>iii</sc> ) single-ion magnet where the weak equatorial ligand field is created entirely by using a macrocycle.
Topics & Concepts
Pentagonal bipyramidal molecular geometryMagnetIonCrystallographyLigand (biochemistry)AnisotropyChemistryLanthanideScope (computer science)Materials sciencePhysicsComputer scienceOrganic chemistryOpticsBiochemistryReceptorQuantum mechanicsProgramming languageMagnetism in coordination complexesAdvanced NMR Techniques and ApplicationsLanthanide and Transition Metal Complexes