Silacarboxylic acid-mediated photoredox <i>Z</i>-stereoselective fluoroalkylation of alkynes
Chunhui Yang, Zhifeng Ma, Hengyuan Zhao, Zhi Li, Guokai Li, Jingchao Chen, Baomin Fan
Abstract
The photoredox-catalyzed fluoroalkylation of alkynes has been developed with silacarboxylic acid as an easily accessible, safe, and highly stable novel halogen-atom transfer mediator.
Topics & Concepts
ChemistryStereoselectivityCombinatorial chemistryStereochemistryOrganic chemistryCatalysisFluorine in Organic Chemistry