Explaining the effect of in-plane strain on thermal degradation kinetics of Cu/W nano-multilayers
Javier F. Troncoso, Giacomo Lorenzin, Claudia Cancellieri, Vladyslav Turlo
Abstract
Thermal annealing experiments evidence opposite effect on the degradation kinetics of Cu/W nano-multilayers from compressive to tensile in-plane strain. Besides higher activation energy, nano-multilayers with tensile strains degrade to nanocomposites faster than those with compressive strains. By assuming a vacancy-driven diffusion mechanism of degradation, we applied ab initio calculations to quantify different contributions to the corresponding diffusion coefficients in relation to in-plane strain. The average vacancy formation energy increases as the strain changes from compressive to tensile, which explains the higher experimental activation energy. The bulk in-plane and out-of-plane vacancy migration energies and corresponding diffusion prefactors highlight that enhanced transformation rate under tension can be explained by the segregation of non-equilibrium W vacancies to Cu/W interfaces. These theoretical insights are grounded in and serve to interpret the experimental observations, offering a coherent understanding of the strain-dependent thermal degradation kinetics.