Schiff-base molecules and COFs as metal-free catalysts or silver supports for carboxylation of alkynes with CO<sub>2</sub>
Lin Zhang, Ran Bu, Xiaoyan Liu, Peng-Fei Mu, En‐Qing Gao
Abstract
Triformylphloroglucinol-derived imine molecules and COFs act as transition-metal-free catalysts for the title reaction, and COFs are also composited with Ag nanoparticles to afford higher activity.
Topics & Concepts
CatalysisImineChemistryMoleculeCarboxylationSchiff baseTransition metalCombinatorial chemistryMetalBase (topology)Polymer chemistryOrganic chemistryMathematicsMathematical analysisCarbon dioxide utilization in catalysisCO2 Reduction Techniques and CatalystsCovalent Organic Framework Applications