Electrochemical sensor formed from poly(3,4-ethylenedioxyselenophene) and nitrogen-doped graphene composite for dopamine detection
Aygul Kadir, Ruxangul Jamal, Tursun Abdiryim, Nurbiya Sawut, Yuzhu Che, Zulpikar Helil, Hujun Zhang
Abstract
polymerization method. Its structure and properties were then compared with those of the composites of poly(3,4-ethylenedioxythiophene) (PEDOT)/nitrogen-doped graphene (PEDOT/N-Gr), which were prepared by the same methods. FT-IR, Raman, UV-vis, XPS, mapping and SEM investigated the structure and morphology of these composites. These revealed that PEDOS/N-Gr had a higher conjugation degree than PEDOT/N-Gr. The synergetic effect between PEDOS and N-Gr was beneficial for the formation of a homogenous surface coating. The cyclic voltammetry (CV) and differential pulse voltammetry (DPV) methods were conducted for electrochemical detection of DA. Compared with PEDOT/N-Gr, the PEDOS/N-Gr displayed an enhanced sensitivity and electrocatalytic performance for DA detection with linear ranges of 0.008-80 μM (PEDOT/N-Gr: 0.04-70 μM) and limits of detection (LOD) of 0.0066 μM (S/N = 3) (PEDOT/N-Gr: 0.018 μM (S/N = 3)).