Reorientable fluorinated aryl rings in triangular channel Fe-MOFs: an investigation on CO<sub>2</sub>–matrix interactions
Jacopo Perego, Charl X. Bezuidenhout, Alessandro Pedrini, Silvia Bracco, Mattia Negroni, Angiolina Comotti, Piero Sozzani
Abstract
Flexible aryl rings in fluorinated Fe-MOFs point C–F dipoles towards the corner of triangular channels capturing efficiently CO<sub>2</sub> molecules.
Topics & Concepts
ArylMoleculeMatrix (chemical analysis)Triangular matrixDipoleMaterials scienceAromaticityCrystallographyChemistryPure mathematicsMathematicsOrganic chemistryComposite materialAlkylInvertible matrixMetal-Organic Frameworks: Synthesis and ApplicationsCovalent Organic Framework ApplicationsInorganic Fluorides and Related Compounds